S15, sixteen). These lifetimes are according to the O(a hundred) 12 months residence time of partially-labile and semi-refractory dissolved natural carbon41 and ligands in deep waters on the Atlantic42,forty three. Greater ligand lifetime raises the product parameter ratio γ/λ from the info-optimized worth of 4398.0 s to 5497.5 s, shifting the program in direction of an “iron-replete, macronutrient constrained�?regime22, accumulating a larger pool of ligands on account of slower costs of decay across all MOC strengths. For a longer time-lived ligands support a bigger availability of iron, causing a far more full drawdown of area macronutrients, significantly during the iron-confined Southern and Pacific Oceans. In distinction, decreasing ligand lifetime lowers the model γ/λ ratio from the information-optimized worth of 4398.0 s to 3298.five s, shifting the technique in direction of an “iron-limited, macronutrient replete�?regime22. Extra swift ligand decay minimizes ligand standing inventory and lowers the overall availability of iron, causing considerably less complete macronutrient intake inside the Surface Southern and Pacific Oceans, once more across all MOC strengths. Even though the gradient of your MOC-atmospheric pCO2 romantic relationship is sensitive to perturbations from the ligand lifetime, a detrimental In general correlation remains sturdy.

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